Information card for entry 4337893

Structure parameters

• Chemical name: [RhH(dpp3)(P(ArF)2BH3)(PH(ArF)2BH3)][BArF4]
• Formula: C106.69 H68.46 B3 F53.23 P4 Rh
• Calculated formula: C106.687 H68.458 B3 F53.229 P4 Rh
• Title of publication: Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine-Boranes.
• Authors of publication: Hooper, Thomas N.; Huertos, Miguel A.; Jurca, Titel; Pike, Sebastian D.; Weller, Andrew S.; Manners, Ian
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 7
• Pages of publication: 3716
• a: 16.4783 ± 0.0002 Å
• b: 18.4893 ± 0.0002 Å
• c: 21.272 ± 0.0003 Å
• α: 79.5983 ± 0.0005°
• β: 74.0583 ± 0.0006°
• γ: 64.6987 ± 0.0006°
• Cell volume: 5619.05 ± 0.12 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0859
• Residual factor for significantly intense reflections: 0.0629
• Weighted residual factors for all reflections: 0.1857
• Weighted residual factors for significantly intense reflections: 0.1623
• Weighted residual factors for all reflections included in the refinement: 0.1855
• Goodness-of-fit parameter for all reflections included in the refinement: 0.8277
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No