Synthesis of the water soluble ligands dmPTA and dmoPTA and the complex [RuClCp(HdmoPTA)(PPh(3))](OSO(2)CF(3)) (dmPTA = N,N'-Dimethyl-1,3,5-triaza-7-phosphaadamantane, dmoPTA = 3,7-Dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, HdmoPTA = 3,7-H-3,7-Dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane).
Authors of publication
Mena-Cruz, Adrian; Lorenzo-Luis, Pablo; Romerosa, Antonio; Saoud, Mustapha; Serrano-Ruiz, Manuel
Journal of publication
Inorganic chemistry
Year of publication
2007
Journal volume
46
Journal issue
15
Pages of publication
6120 - 6128
a
9.162 ± 0.005 Å
b
14.336 ± 0.005 Å
c
15.123 ± 0.005 Å
α
77.226 ± 0.005°
β
74.345 ± 0.005°
γ
77.086 ± 0.005°
Cell volume
1836.7 ± 1.3 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
9
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0911
Residual factor for significantly intense reflections
0.0517
Weighted residual factors for significantly intense reflections
0.1163
Weighted residual factors for all reflections included in the refinement
0.1737
Goodness-of-fit parameter for all reflections included in the refinement
