Information card for entry 4339158

Structure parameters

• Formula: C52 H42 Cl4 N4 Os P2
• Calculated formula: C52 H42 Cl4 N4 Os P2
• SMILES: [P](c1ccccc1)(c1ccccc1)([Os]1(C#N)(C#N)([n]2cccc3c2c2c(ccc[n]12)cc3)[P](c1ccccc1)(c1ccccc1)c1ccccc1)c1ccccc1.C(Cl)Cl.C(Cl)Cl
• Title of publication: cis-Dicyanoosmium(II) diimine complexes bearing phosphine or sulfoxide ligands: spectroscopic and luminescent studies.
• Authors of publication: Lai, Siu-Wai; Chan, Queenie K.-W.; Zhu, Nianyong; Che, Chi-Ming
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 26
• Pages of publication: 11003 - 11016
• a: 20.479 ± 0.004 Å
• b: 10.639 ± 0.002 Å
• c: 23.738 ± 0.005 Å
• α: 90°
• β: 113.88 ± 0.03°
• γ: 90°
• Cell volume: 4729 ± 2 ų
• Cell temperature: 253 ± 2 K
• Ambient diffraction temperature: 253 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0353
• Residual factor for significantly intense reflections: 0.0303
• Weighted residual factors for significantly intense reflections: 0.0811
• Weighted residual factors for all reflections included in the refinement: 0.0825
• Goodness-of-fit parameter for all reflections included in the refinement: 1.146
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No