Information card for entry 4339556

Structure parameters

• Formula: C35 H41 Cl O5 P3 Rh
• Calculated formula: C35 H41 Cl O5 P3 Rh
• SMILES: C(O)[P]1(CO)CO[P](c2ccccc2)(c2ccccc2)[Rh]1(Cl)[P](c1ccccc1)(c1ccccc1)c1ccccc1.CO.CO
• Title of publication: Formation of a phosphine-phosphinite ligand in RhCl(PRR'2)[P,P-R'(R)POCH2P(CH2OH)2] and R'H from cis-RhCl(PRR'2)2[P(CH2OH)3] via P-C bond cleavage.
• Authors of publication: Lorenzini, Fabio; Patrick, Brian O.; James, Brian R.
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 21
• Pages of publication: 8998 - 9002
• a: 10.4723 ± 0.0011 Å
• b: 11.6071 ± 0.0013 Å
• c: 14.5877 ± 0.0015 Å
• α: 87.553 ± 0.006°
• β: 78.799 ± 0.005°
• γ: 83.749 ± 0.005°
• Cell volume: 1728.6 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0513
• Residual factor for significantly intense reflections: 0.0318
• Weighted residual factors for significantly intense reflections: 0.0614
• Weighted residual factors for all reflections included in the refinement: 0.0678
• Goodness-of-fit parameter for all reflections included in the refinement: 1.01
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No