Information card for entry 4339650

Structure parameters

• Formula: C28 H63 Cl Mo N O2 Si2
• Calculated formula: C28 H63 Cl Mo N O2 Si2
• Title of publication: Synthesis and reactivity of [(silox)2Mo=NR]2Hg (R=tBu, tAmyl; silox=OSitBu3): unusual thermal stability and ready nucleophilic cleavage rationalized by electronic factors.
• Authors of publication: Rosenfeld, Devon C.; Wolczanski, Peter T.; Barakat, Khaldoon A.; Buda, Corneliu; Cundari, Thomas R.; Schroeder, Frank C.; Lobkovsky, Emil B.
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 23
• Pages of publication: 9715 - 9735
• a: 8.6651 ± 0.0007 Å
• b: 12.4896 ± 0.0009 Å
• c: 17.2926 ± 0.0013 Å
• α: 98.231 ± 0.002°
• β: 99.95 ± 0.002°
• γ: 97.4 ± 0.002°
• Cell volume: 1801.6 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0526
• Residual factor for significantly intense reflections: 0.0388
• Weighted residual factors for significantly intense reflections: 0.0931
• Weighted residual factors for all reflections included in the refinement: 0.0993
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No