Information card for entry 4340418

Structure parameters

• Formula: C54 H55 F6 O11 P5 Ru S2
• Calculated formula: C54 H55 F6 O11 P5 Ru S2
• Title of publication: Highly electrophilic, 16-electron [Ru(P(OMe)(OH)(2))(dppe)(2)](2+) complex turns H(2)(g) into a strong acid and splits a Si-H bond heterolytically. Synthesis and structure of the novel phosphorous acid complex [Ru(P(OH)(3))(dppe)(2)](2+).
• Authors of publication: Nagaraja, C. M.; Nethaji, Munirathinam; Jagirdar, Balaji R.
• Journal of publication: Inorganic chemistry
• Year of publication: 2005
• Journal volume: 44
• Journal issue: 12
• Pages of publication: 4145 - 4147
• a: 13.7747 ± 0.0015 Å
• b: 14.319 ± 0.0015 Å
• c: 29.377 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5794.3 ± 1.1 ų
• Cell temperature: 290 K
• Ambient diffraction temperature: 290 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.031
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.0888
• Weighted residual factors for all reflections included in the refinement: 0.0908
• Goodness-of-fit parameter for all reflections included in the refinement: 0.697
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No