Information card for entry 4340544

Structure parameters

• Formula: C52 H58 Cl8 F6 O6 P4 Pt2 S2
• Calculated formula: C52 H58 Cl8 F6 O6 P4 Pt2 S2
• SMILES: c12ccc3c4c(ccc([P](C(C)C)([Pt]5([P@]1(c1ccccc1)Cl)[Cl][Pt]1([P@@](c6ccc7c8c(ccc([P]1(C(C)C)C(C)C)c68)CC7)(c1ccccc1)Cl)[Cl]5)C(C)C)c24)CC3.[O-]S(=O)(=O)C(F)(F)F.C(Cl)Cl.FC(F)(F)S(=O)(=O)[O-].C(Cl)Cl
• Title of publication: Synthetic and Structural Study of the Coordination Chemistry of a peri-Backbone-Supported Phosphino-Phosphonium Salt.
• Authors of publication: Ray, Matthew J.; Bühl, Michael; Taylor, Laurence J.; Athukorala Arachchige, Kasun S.; Slawin, Alexandra M. Z.; Kilian, Petr
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 16
• Pages of publication: 8538 - 8547
• a: 8.54 ± 0.001 Å
• b: 12.7016 ± 0.0014 Å
• c: 15.366 ± 0.002 Å
• α: 102.196 ± 0.008°
• β: 101.379 ± 0.007°
• γ: 106.672 ± 0.008°
• Cell volume: 1500.3 ± 0.3 ų
• Cell temperature: 125 K
• Ambient diffraction temperature: 125 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.053
• Weighted residual factors for all reflections included in the refinement: 0.1431
• Goodness-of-fit parameter for all reflections included in the refinement: 1.056
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No