Information card for entry 4340879

Structure parameters

• Formula: C32 H32 F6 N8 O Os P2
• Calculated formula: C32 H32 F6 N8 O Os P2
• SMILES: [Os]12([P](C)(C)c3ccccc3)([P](C)(C)c3ccccc3)([n]3ccccc3c3n1nc(n3)C(F)(F)F)[n]1ccccc1c1n2nc(n1)C(F)(F)F.O
• Title of publication: Os(II) Phosphors with Near-Infrared Emission Induced by Ligand-to-Ligand Charge Transfer Transition.
• Authors of publication: Liao, Jia-Ling; Chi, Yun; Liu, Shih-Hung; Lee, Gene-Hsiang; Chou, Pi-Tai; Huang, Hao-Xiang; Su, Yu-De; Chang, Chih-Hao; Lin, Jin-Sheng; Tseng, Meu-Rurng
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 17
• Pages of publication: 9366 - 9374
• a: 10.3275 ± 0.0006 Å
• b: 17.2508 ± 0.0011 Å
• c: 19.5265 ± 0.0011 Å
• α: 90°
• β: 102.25 ± 0.0014°
• γ: 90°
• Cell volume: 3399.6 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0464
• Residual factor for significantly intense reflections: 0.0353
• Weighted residual factors for significantly intense reflections: 0.0691
• Weighted residual factors for all reflections included in the refinement: 0.0737
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No