Information card for entry 4341452

Structure parameters

• Formula: C22 H18 I2 N6 Ni
• Calculated formula: C22 H18 I2 N6 Ni
• SMILES: I[Ni]12(I)([N](c3ccccc3)=Nc3[n]1cccc3)[N](=Nc1[n]2cccc1)c1ccccc1
• Title of publication: Ligand-Centered Redox in Nickel(II) Complexes of 2-(Arylazo)pyridine and Isolation of 2-Pyridyl-Substituted Triaryl Hydrazines via Catalytic N-Arylation of Azo-Function.
• Authors of publication: Sengupta, Debabrata; Ghosh, Pradip; Chatterjee, Tanmay; Datta, Harashit; Paul, Nanda D.; Goswami, Sreebrata
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Pages of publication: 141105122752002
• a: 10.209 ± 0.005 Å
• b: 15.357 ± 0.005 Å
• c: 14.586 ± 0.005 Å
• α: 90 ± 0.005°
• β: 93.112 ± 0.005°
• γ: 90 ± 0.005°
• Cell volume: 2283.4 ± 1.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0392
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.0704
• Weighted residual factors for all reflections included in the refinement: 0.0742
• Goodness-of-fit parameter for all reflections included in the refinement: 1.052
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No