Information card for entry 4343808

Structure parameters

• Chemical name: K10 Na12 ((Co3 (Si W9 O33 (O H)) (Si W8 O29 (O H)2))2) (H2 O)49
• Formula: Co6 K10 Na2 O179 Si4 W34
• Calculated formula: Co6 K10 Na2 O179 Si4 W34
• SMILES: O=[W]123(=O)O[W]45(O[W]678(=O)=[O][Co]9%10%11%12[O]%13%14[Si]%15%16[O]%17%18[W]%19%20%21%22=[O][Co]%23%24%13([O]=[W]%13%25(=O)(=[O]9)O[W]9%26(O[W]%27%17(O[W]%17%28%29(O[W]%30(O[W]%31(O%17)(O[W]%18(O%27)(=O)(O%21)=[O][Co]%17%18%14([O]%10[Si]%10([O]34)[O]34[W]%14%21(O[W]%27(=O)(O6)(O[W](=O)(O7)(O[W]3(O[W]4(O%14)(O2)(=[O]%17)=O)(O%21)([O]%24%18)=O)([O]%11%23)[O]8%10%27)O5)(O1)=O)[O]=%31)(=O)[O]%15%29%30)(O[W](=O)(O%28)(O9)([O]%16%13%26)O%25)(=O)=[O]%12)=O)(O%22)=O)(=O)O%20)[O]=[W]1234[O]56[W]78(=O)(O3)=[O][Co]39%10%11[O]%12%13[Co]%14%15%16%17[O]=[W]%18%20%21(O[W]%22%23(=O)([O]%24[W]%25(O[W]%26%27%28(O[W]%29(=O)(O[W]%30%31(=O)(O[W]%32(O[W]([O]%18%32[Si]%24([O]%28%29%31)[O]%11%17)(O%20)(=O)(O%23)O%26)([O]%15[Co]%13([O]=%19)([O]=[W]%11%13(O[W]%15%17(O[W]5(O1)(O[W]15%18(=O)[O]%19%20[W](=O)(=[O]3)(O7)(O5)O[W]%19(O[W](=O)(O1)(O%11)([O]%13%15[Si]6%12%20)O%17)(=[O]%16)(=O)O%18)(=O)O8)(=O)O2)(=[O]%14)=O)([O]9%30)[O]=4)(O%21)=O)O%27)(O%25)=[O]%10)=O)(O%22)(=O)=O)=O)=O)(=O)=O.[Na+].[Na+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O
• Title of publication: Cobalt containing silicotungstate sandwich dimer [{Co3 (B-beta-Si W9 O33 (O H)) (B-beta-Si W8 O29 (O H)2)}2](22-)
• Authors of publication: Bassil, B.S.; Kortz, U.; Keita, B.; Tigan, A.S.; Clemente-Juan, J.M.; de Oliveira, P.; Nadjo, L.
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 9360 - 9368
• a: 19.9466 Å
• b: 24.6607 Å
• c: 34.0978 Å
• α: 90°
• β: 102.175°
• γ: 90°
• Cell volume: 16395.4 ų
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No