Information card for entry 4344089

Structure parameters

• Formula: C4 H6 Ce4 Cs1.5 Na8.5 O97.5 Si2 W18
• Calculated formula: C4 H6 Ce4 Cs1.5 Na8.5 O97.5 Si2 W18
• Title of publication: Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW9O34](10-) Polyoxometalate.
• Authors of publication: Duval, Sylvain; Béghin, Sébastien; Falaise, Clément; Trivelli, Xavier; Rabu, Pierre; Loiseau, Thierry
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 17
• Pages of publication: 8271 - 8280
• a: 25.7962 ± 0.0008 Å
• b: 19.0538 ± 0.0005 Å
• c: 18.0991 ± 0.0005 Å
• α: 90°
• β: 100.523 ± 0.0015°
• γ: 90°
• Cell volume: 8746.4 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100.01 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0318
• Residual factor for significantly intense reflections: 0.0271
• Weighted residual factors for significantly intense reflections: 0.0611
• Weighted residual factors for all reflections included in the refinement: 0.0633
• Goodness-of-fit parameter for all reflections included in the refinement: 1.093
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No