Information card for entry 4344423

Structure parameters

• Chemical name: Bis(cyano-κC)[2-(3,5-diphenyl-1H-pyrrol-2-yl-κN)pyridinato-κN]gold(iii) diethyl ether solvate (2:1)
• Formula: C50 H40 Au2 N8 O
• Calculated formula: C50 H40 Au2 N8 O
• Title of publication: Monocyclometalated Gold(III) Complexes Bearing π-Accepting Cyanide Ligands: Syntheses, Structural, Photophysical, and Electrochemical Investigations.
• Authors of publication: Szentkuti, Alexander; Garg, Jai Anand; Blacque, Olivier; Venkatesan, Koushik
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 22
• Pages of publication: 10748 - 10760
• a: 4.8031 ± 0.0002 Å
• b: 11.6531 ± 0.0005 Å
• c: 19.9543 ± 0.0011 Å
• α: 75.611 ± 0.004°
• β: 84.488 ± 0.004°
• γ: 84.492 ± 0.003°
• Cell volume: 1073.81 ± 0.09 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0828
• Residual factor for significantly intense reflections: 0.0632
• Weighted residual factors for significantly intense reflections: 0.1525
• Weighted residual factors for all reflections included in the refinement: 0.1576
• Goodness-of-fit parameter for all reflections included in the refinement: 1.138
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No