Information card for entry 4345571

Structure parameters

• Formula: C38 H76 Cl3 N6 O2 P3 Pt3
• Calculated formula: C38 H76 Cl3 N6 O2 P3 Pt3
• SMILES: [Pt]123([Pt]4([Pt]1(Cl)([P]12N(C(C)(C)C)C=CN1C(C)(C)C)[P]14N(C(C)(C)C)C=CN1C(C)(C)C)(Cl)[P]13N(C(C)(C)C)C=CN1C(C)(C)C)Cl.O1CCCC1.O1CCCC1
• Title of publication: Phosphenium Hydride Reduction of [(cod)MX2] (M = Pd, Pt; X = Cl, Br): Snapshots on the Way to Phosphenium Metal(0) Halides and Synthesis of Metal Nanoparticles.
• Authors of publication: Nickolaus, Jan; Imbrich, Dominik A.; Schlindwein, Simon H.; Geyer, Adrian H.; Nieger, Martin; Gudat, Dietrich
• Journal of publication: Inorganic chemistry
• Year of publication: 2017
• Journal volume: 56
• Journal issue: 5
• Pages of publication: 3071 - 3080
• a: 14.1385 ± 0.0007 Å
• b: 16.4928 ± 0.0008 Å
• c: 21.4412 ± 0.001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4999.7 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0402
• Residual factor for significantly intense reflections: 0.0297
• Weighted residual factors for significantly intense reflections: 0.0615
• Weighted residual factors for all reflections included in the refinement: 0.0644
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No