Information card for entry 4346553

Structure parameters

• Common name: [NMe4][TMS-S], 6
• Chemical name: Tetramethylammonium-trimethylsilylthiolate aceonitrile solvate
• Formula: C9 H24 N2 S Si
• Calculated formula: C9 H24 N2 S Si
• Title of publication: Synthesis of organic (trimethylsilyl)chalcogenolate salts Cat[TMS-E] (E = S, Se, Te): the methylcarbonate anion as a desilylating agent.
• Authors of publication: Finger, Lars H.; Scheibe, Benjamin; Sundermeyer, Jörg
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 19
• Pages of publication: 9568 - 9575
• a: 7.6236 ± 0.0011 Å
• b: 7.6281 ± 0.0011 Å
• c: 13.2227 ± 0.0018 Å
• α: 90°
• β: 104.094 ± 0.004°
• γ: 90°
• Cell volume: 745.8 ± 0.18 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 5
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.1308
• Residual factor for significantly intense reflections: 0.0784
• Weighted residual factors for significantly intense reflections: 0.1331
• Weighted residual factors for all reflections included in the refinement: 0.1505
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No