Information card for entry 4348031

Structure parameters

• Common name: [(Mn3Mo14O56)@Ag64(C6H9)38(CF3COO)8](OH).10CH3CN.2H2O
• Formula: C264 H313 Ag64 F24 Mn3 Mo14 N10 O75
• Calculated formula: C264 H313 Ag64 F24 Mn3 Mo14 N10 O75
• Title of publication: [Mn(III)Mn(IV)2Mo14O56](17-): A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster.
• Authors of publication: Wang, Jian-Yu; Liu, Kuan-Guan; Guan, Zong-Jie; Nan, Zi-Ang; Lin, Yu-Mei; Wang, Quan-Ming
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 14
• Pages of publication: 6833 - 6835
• a: 37.9167 ± 0.0011 Å
• b: 25.2465 ± 0.0005 Å
• c: 41.6881 ± 0.0012 Å
• α: 90°
• β: 105.587 ± 0.003°
• γ: 90°
• Cell volume: 38438.9 ± 1.8 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0904
• Residual factor for significantly intense reflections: 0.0576
• Weighted residual factors for significantly intense reflections: 0.1404
• Weighted residual factors for all reflections included in the refinement: 0.1588
• Goodness-of-fit parameter for all reflections included in the refinement: 1.118
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No