Information card for entry 4348284

Structure parameters

• Formula: C26 H50 Au3 Cl2 F3 N4 O3 P2 S2
• Calculated formula: C26 H50 Au3 Cl2 F3 N4 O3 P2 S2
• SMILES: C1(N(C=CN1[P](C(C)(C)C)(C(C)(C)C)[Au]Cl)[P](C(C)(C)C)(C(C)(C)C)[Au]Cl)=[Au][S](C)C.FC(F)(S(=O)(=O)[O-])F.N#CC.C(#N)C
• Title of publication: Bonding, Luminescence, Metallophilicity in Linear Au3 and Au2Ag Chains Stabilized by Rigid Diphosphanyl NHC Ligands.
• Authors of publication: Ai, Pengfei; Mauro, Matteo; Gourlaouen, Christophe; Carrara, Serena; De Cola, Luisa; Tobon, Yeny; Giovanella, Umberto; Botta, Chiara; Danopoulos, Andreas A.; Braunstein, Pierre
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 17
• Pages of publication: 8527 - 8542
• a: 10.2433 ± 0.0006 Å
• b: 16.1714 ± 0.001 Å
• c: 12.1589 ± 0.0007 Å
• α: 90°
• β: 91.126 ± 0.002°
• γ: 90°
• Cell volume: 2013.7 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 9
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.0354
• Residual factor for significantly intense reflections: 0.0253
• Weighted residual factors for significantly intense reflections: 0.0564
• Weighted residual factors for all reflections included in the refinement: 0.061
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No