Information card for entry 4350130

Structure parameters

• Formula: C53 H46 Cl9 Co Cu2 N17 O16 P6
• Calculated formula: C49.7778 H35.5556 Cl8.88889 Co0.888889 Cu1.77778 N15.1111 O15.1111 P5.33333
• Title of publication: Di- and trinuclear complexes derived from hexakis(2-pyridyloxy)cyclotriphosphazene. Unusual P-O bond cleavage in the formation of [{(L'CuCl)2(Co(NO3)}Cl] (L' = N3P3(OC5H4N)5(O)).
• Authors of publication: Chandrasekhar, Vadapalli; Pandian, Balasubramanian Murugesa; Azhakar, Ramachandran
• Journal of publication: Inorganic chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 9
• Pages of publication: 3510 - 3518
• a: 22.6394 ± 0.0018 Å
• b: 28.2017 ± 0.0018 Å
• c: 45.26 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 28897 ± 4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 70
• Hermann-Mauguin space group symbol: F d d d :2
• Hall space group symbol: -F 2uv 2vw
• Residual factor for all reflections: 0.0755
• Residual factor for significantly intense reflections: 0.0598
• Weighted residual factors for significantly intense reflections: 0.166
• Weighted residual factors for all reflections included in the refinement: 0.1787
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No