Information card for entry 4350444

Structure parameters

• Common name: (TcCl3(DMSO)2)O
• Chemical name: mu2-oxo-bis{trichlorobis(dimethylsulfoxide)technetium(IV)}
• Formula: C8 H24 Cl6 O5 S4 Tc2
• Calculated formula: C8 H24 Cl6 O5 S4 Tc2
• SMILES: CS(=[O][Tc]([O]=S(C)C)(Cl)(Cl)(Cl)O[Tc]([O]=S(C)C)([O]=S(C)C)(Cl)(Cl)Cl)C
• Title of publication: Technetium tetrachloride as a precursor for small technetium(IV) complexes.
• Authors of publication: Hagenbach, Adelheid; Yegen, Eda; Abram, Ulrich
• Journal of publication: Inorganic chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 18
• Pages of publication: 7331 - 7338
• a: 11.335 ± 0.002 Å
• b: 9.463 ± 0.001 Å
• c: 13.116 ± 0.002 Å
• α: 90°
• β: 113.13 ± 0.01°
• γ: 90°
• Cell volume: 1293.8 ± 0.3 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 13
• Hermann-Mauguin space group symbol: P 1 2/c 1
• Hall space group symbol: -P 2yc
• Residual factor for all reflections: 0.1514
• Residual factor for significantly intense reflections: 0.0966
• Weighted residual factors for significantly intense reflections: 0.2425
• Weighted residual factors for all reflections included in the refinement: 0.2701
• Goodness-of-fit parameter for all reflections included in the refinement: 0.953
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No