Information card for entry 4350703

Structure parameters

• Formula: C19 H48 Co N4 Si4
• Calculated formula: C19 H48 Co N4 Si4
• SMILES: [Co]([n]1cn(cc1)C(C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Carbene rearrangements in three-coordinate N-heterocyclic carbene complexes of cobalt(II) bis(trimethylsilyl)amide.
• Authors of publication: Day, Benjamin M.; Pal, Kuntal; Pugh, Thomas; Tuck, Jessica; Layfield, Richard A.
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 19
• Pages of publication: 10578 - 10584
• a: 11.2938 ± 0.0007 Å
• b: 23.6539 ± 0.0017 Å
• c: 11.9788 ± 0.0007 Å
• α: 90°
• β: 108.216 ± 0.007°
• γ: 90°
• Cell volume: 3039.7 ± 0.4 ų
• Cell temperature: 150 ± 0.16 K
• Ambient diffraction temperature: 150 ± 0.16 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0927
• Residual factor for significantly intense reflections: 0.051
• Weighted residual factors for significantly intense reflections: 0.0918
• Weighted residual factors for all reflections included in the refinement: 0.1062
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No