Information card for entry 4514630

Structure parameters

• Formula: C29 H33 F6 N3 O11 S2 U
• Calculated formula: C29 H33 F6 N3 O11 S2 U
• Title of publication: Breaking C‒O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes
• Authors of publication: Monsigny, Louis; Thuéry, Pierre; Berthet, Jean-Claude; Cantat, Thibault
• Journal of publication: ACS Catalysis
• Year of publication: 2019
• Journal volume: 9
• Journal issue: 10
• Pages of publication: 9025
• a: 9.2981 ± 0.0004 Å
• b: 22.059 ± 0.0017 Å
• c: 18.3163 ± 0.0012 Å
• α: 90°
• β: 102.709 ± 0.004°
• γ: 90°
• Cell volume: 3664.8 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0576
• Residual factor for significantly intense reflections: 0.0367
• Weighted residual factors for significantly intense reflections: 0.082
• Weighted residual factors for all reflections included in the refinement: 0.0882
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No