Information card for entry 4515746

Structure parameters

• Chemical name: N-(2,4,6-trimethyl-phenyl)-2-di-(3,5-ditrifluoromethylphenyl)- phosphinylchlorogold(i)-pyridinium hexafluoroantimonate acetonitrile
• Formula: C32 H24 Au Cl F18 N2 P Sb
• Calculated formula: C32 H24 Au Cl F18 N2 P Sb
• Title of publication: N-Arylpyridiniophosphines: Synthesis, Structure, and Applications in Au(I) Catalysis
• Authors of publication: Tinnermann, Hendrik; Nicholls, Leo D. M.; Johannsen, Tim; Wille, Christian; Golz, Christopher; Goddard, Richard; Alcarazo, Manuel
• Journal of publication: ACS Catalysis
• Year of publication: 2018
• Journal volume: 8
• Journal issue: 11
• Pages of publication: 10457
• a: 8.7962 ± 0.0006 Å
• b: 27.1915 ± 0.0018 Å
• c: 16.076 ± 0.0014 Å
• α: 90°
• β: 103.535 ± 0.009°
• γ: 90°
• Cell volume: 3738.3 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0307
• Residual factor for significantly intense reflections: 0.0252
• Weighted residual factors for significantly intense reflections: 0.0601
• Weighted residual factors for all reflections included in the refinement: 0.0633
• Goodness-of-fit parameter for all reflections included in the refinement: 1.109
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No