Information card for entry 7000238

Structure parameters

• Formula: C56 H60 P6 Pt2
• Calculated formula: C56 H60 P6 Pt2
• SMILES: [Pt]1(P2[Pt](P12)([P](CC)(c1ccccc1)c1ccccc1)[P](CC)(c1ccccc1)c1ccccc1)([P](CC)(c1ccccc1)c1ccccc1)[P](CC)(c1ccccc1)c1ccccc1
• Title of publication: Reactions of R2P‒P(SiMe3)Li with [(R′3P)2PtCl2]. A general and efficient entry to phosphanylphosphinidene complexes of platinum. Syntheses and structures of [(η2-PPiPr2)Pt(p-Tol3P)2], [(η2-PPtBu2)Pt(p-Tol3P)2], [{η2-PP(NiPr2)2}Pt(p-Tol3P)2] and [{(Et2PhP)2Pt}2P2]
• Authors of publication: Domańska-Babul, Wioleta; Chojnacki, Jaroslaw; Matern, Eberhard; Pikies, Jerzy
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 1
• Pages of publication: 146 - 151
• a: 19.5441 ± 0.0016 Å
• b: 9.6862 ± 0.001 Å
• c: 29.7907 ± 0.0017 Å
• α: 90°
• β: 107.751 ± 0.009°
• γ: 90°
• Cell volume: 5371.1 ± 0.8 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1777
• Residual factor for significantly intense reflections: 0.1227
• Weighted residual factors for significantly intense reflections: 0.2875
• Weighted residual factors for all reflections included in the refinement: 0.3115
• Goodness-of-fit parameter for all reflections included in the refinement: 1.14
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No