Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the “pseudo” tetraphospha-metallocenes [M(η-P2C3But3)2], (M = Ni, Pd, Pt)
Authors of publication
Cloke, F. Geoffrey N.; Green, Jennifer C.; Hitchcock, Peter B.; Nixon, John F.; Suter, James L.; Wilson, D. James
Journal of publication
Dalton Transactions
Year of publication
2009
Journal issue
7
Pages of publication
1164 - 1171
a
11.046 ± 0.003 Å
b
28.537 ± 0.009 Å
c
16.175 ± 0.005 Å
α
90°
β
105.12 ± 0.02°
γ
90°
Cell volume
4922 ± 3 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
173 ± 2 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.1689
Residual factor for significantly intense reflections
0.0754
Weighted residual factors for significantly intense reflections
0.1398
Weighted residual factors for all reflections included in the refinement
0.178
Goodness-of-fit parameter for all reflections included in the refinement
