Information card for entry 7000519

Structure parameters

• Common name: (Co2I4(dppcbO3))
• Chemical name: [Co2I4(dppcbO3)]
• Formula: C105.8 H93.6 Cl3.6 Co4 I8 O7 P8
• Calculated formula: C105.8 H93.6 Cl3.6 Co4 I8 O7 P8
• Title of publication: Regio- and chemoselective oxidation of the bis(bidentate) phosphine cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphino)cyclobutane via cobalt(II) mediated dioxygen activation
• Authors of publication: Fessler, Markus; Eller, Sylvia; Bachmann, Christian; Gutmann, Rene; Trettenbrein, Barbara; Kopacka, Holger; Mueller, Thomas; Brueggeller, Peter
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 8
• Pages of publication: 1383
• a: 14.491 ± 0.003 Å
• b: 20.193 ± 0.004 Å
• c: 21.528 ± 0.004 Å
• α: 93.74 ± 0.03°
• β: 97.49 ± 0.03°
• γ: 110.54 ± 0.03°
• Cell volume: 5807 ± 2 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0943
• Residual factor for significantly intense reflections: 0.0791
• Weighted residual factors for significantly intense reflections: 0.2105
• Weighted residual factors for all reflections included in the refinement: 0.2495
• Goodness-of-fit parameter for all reflections included in the refinement: 0.978
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No