Information card for entry 7000651

Structure parameters

• Formula: C34 H54 O2 Ru Si4
• Calculated formula: C34 H53 O2 Ru Si4
• SMILES: [Ru]1234(=[Si](OC(c5ccccc5)c5ccccc5)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)(C#[O])[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds
• Authors of publication: Ochiai, Mitsuyoshi; Hashimoto, Hisako; Tobita, Hiromi
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 10
• Pages of publication: 1812 - 1814
• a: 9.6657 ± 0.0004 Å
• b: 19.8503 ± 0.0016 Å
• c: 20.2818 ± 0.0017 Å
• α: 75.303 ± 0.005°
• β: 79.313 ± 0.005°
• γ: 87.413 ± 0.003°
• Cell volume: 3698.8 ± 0.5 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1482
• Residual factor for significantly intense reflections: 0.1316
• Weighted residual factors for significantly intense reflections: 0.3149
• Weighted residual factors for all reflections included in the refinement: 0.3256
• Goodness-of-fit parameter for all reflections included in the refinement: 1.19
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No