Information card for entry 7000672

Structure parameters

• Common name: (eta$3!-allyl)-bis(triphenylphosphine)-nickel (ii) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate and (eta$3!-allyl)- (triphenylstibine)-(triphenylphosphine)-nickel (ii) tetrakis(3,5- bis(trifluoromethyl)phenyl)borate
• Chemical name: (η^3^-allyl)-bis(triphenylphosphine)-nickel (II) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate and (η^3^-allyl)-(triphenylstibine)-(triphenylphosphine)-nickel (II) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
• Formula: C71 H47 B F24 Ni P1.54 Sb0.46
• Calculated formula: C71 H47 B F24 Ni P1.537 Sb0.463
• Title of publication: Oligomerization of styrenes mediated by cationic allyl nickel complexes containing triphenylstibine or triphenylarsine
• Authors of publication: Jiménez-Tenorio, Manuel; Carmen Puerta, M.; Salcedo, Isabel; Valerga, Pedro; de los Ríos, Isaac; Mereiter, Kurt
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 10
• Pages of publication: 1842 - 1852
• a: 13.093 ± 0.003 Å
• b: 14.56 ± 0.003 Å
• c: 17.565 ± 0.004 Å
• α: 75.09 ± 0.03°
• β: 81.42 ± 0.03°
• γ: 88.28 ± 0.03°
• Cell volume: 3199.4 ± 1.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0937
• Residual factor for significantly intense reflections: 0.0772
• Weighted residual factors for significantly intense reflections: 0.1448
• Weighted residual factors for all reflections included in the refinement: 0.1535
• Goodness-of-fit parameter for all reflections included in the refinement: 1.076
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No