Information card for entry 7000674

Structure parameters

• Common name: Bromo-(tri-hapto-2-methyl-allyl)-(triphenylarsine) nickel (ii)
• Chemical name: Bromo-(tri-hapto-2-methyl-allyl)-(triphenylarsine) nickel (II)
• Formula: C22 H22 As Br Ni
• Calculated formula: C22 H22 As Br Ni
• SMILES: [Ni]12([As](c3ccccc3)(c3ccccc3)c3ccccc3)(Br)C[C]1(=[CH2]2)C
• Title of publication: Oligomerization of styrenes mediated by cationic allyl nickel complexes containing triphenylstibine or triphenylarsine
• Authors of publication: Jiménez-Tenorio, Manuel; Carmen Puerta, M.; Salcedo, Isabel; Valerga, Pedro; de los Ríos, Isaac; Mereiter, Kurt
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 10
• Pages of publication: 1842 - 1852
• a: 12.021 ± 0.002 Å
• b: 9.9974 ± 0.0018 Å
• c: 17.404 ± 0.003 Å
• α: 90°
• β: 98.246 ± 0.003°
• γ: 90°
• Cell volume: 2070 ± 0.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0368
• Residual factor for significantly intense reflections: 0.0315
• Weighted residual factors for significantly intense reflections: 0.0821
• Weighted residual factors for all reflections included in the refinement: 0.0849
• Goodness-of-fit parameter for all reflections included in the refinement: 1.055
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No