Information card for entry 7000746

Structure parameters

• Chemical name: catena-Poly{dichloro(μ-1,4-bis(bis(bis(2- methoxyphenoxy)phospino)amino)benzene-1κ^2^ P,P':2κ^2^P",P"')(μ-pyrazine-1κN:2κN') dirhodium(I)}
• Formula: C66 H64 Cl2 N4 O16 P4 Rh2
• Calculated formula: C66 H64 Cl2 N4 O16 P4 Rh2
• Title of publication: Di-, tetra- and polynuclear RhI complexes containing phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions
• Authors of publication: Ganesamoorthy, Chelladurai; Balakrishna, Maravanji S.; Mague, Joel T.
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 11
• Pages of publication: 1984 - 1990
• a: 16.9519 ± 0.0009 Å
• b: 11.3413 ± 0.0006 Å
• c: 18.325 ± 0.001 Å
• α: 90°
• β: 110.072 ± 0.001°
• γ: 90°
• Cell volume: 3309.1 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0777
• Residual factor for significantly intense reflections: 0.0467
• Weighted residual factors for significantly intense reflections: 0.1051
• Weighted residual factors for all reflections included in the refinement: 0.1197
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No