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Information card for entry 7000784
Preview
Coordinates | 7000784.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C61 H86 N6 O25 Rh12 Sn |
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Calculated formula | C61 H86 N6 O25 Rh12 Sn |
SMILES | [Sn]1234567([Rh](C8=O)(C(=O)[Rh]5(C(=O)[Rh]78C#[O])C#[O])C#[O])([Rh](C#[O])(C(=O)[Rh]4(C#[O])C#[O])C(=O)[Rh]6(C#[O])C#[O])([Rh](C#[O])(C(=O)[Rh]14C#[O])C(=O)[Rh]2(C(=O)[Rh]3(C1=O)C#[O])C#[O])([Rh](C(=O)[Rh]1C#[O])(C#[O])C4=O).[N+](CC)(CC)(CC)CC.[N+](CC)(CC)(CC)CC.[N+](CC)(CC)(CC)CC.[N+](CC)(CC)(CC)CC.N#CC.N#CC |
Title of publication | The loss of CO from [Rh12(μ12-Sn)(CO)27]4−: Synthesis, spectroscopic and structural characterization of the electron-deficient, icosahedral [Rh12(μ12-Sn)(CO)25]4− and [Rh12(μ12-Sn)(CO)26]4− tetra-anions |
Authors of publication | Femoni, Cristina; Iapalucci, Maria Carmela; Longoni, Giuliano; Tiozzo, Cristina; Zacchini, Stefano; Heaton, Brian T.; Iggo, Johnathan A.; Zanello, Piero; Fedi, Serena; Garland, Marc V.; Li, Chuanzhao |
Journal of publication | Dalton Transactions |
Year of publication | 2009 |
Journal issue | 12 |
Pages of publication | 2217 - 2223 |
a | 12.8773 ± 0.0014 Å |
b | 14.4853 ± 0.0016 Å |
c | 21.568 ± 0.002 Å |
α | 90° |
β | 98.23 ± 0.002° |
γ | 90° |
Cell volume | 3981.7 ± 0.7 Å3 |
Cell temperature | 97 ± 2 K |
Ambient diffraction temperature | 97 ± 2 K |
Number of distinct elements | 6 |
Space group number | 4 |
Hermann-Mauguin space group symbol | P 1 21 1 |
Hall space group symbol | P 2yb |
Residual factor for all reflections | 0.0695 |
Residual factor for significantly intense reflections | 0.0455 |
Weighted residual factors for significantly intense reflections | 0.0886 |
Weighted residual factors for all reflections included in the refinement | 0.0995 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.022 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7000784.html
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