Information card for entry 7001280

Structure parameters

• Chemical name: bis(η^4^-cyclo-octa-1,5-diene)-(μ-N,N'-o-phenylene- bis(salicylaldiminato)-κN,O:N',O')-di-rhodium(I)
• Formula: C36 H38 N2 O2 Rh2
• Calculated formula: C36 H38 N2 O2 Rh2
• SMILES: [Rh]1234([N](c5ccccc5[N]5[Rh]678(Oc9c(C=5)cccc9)[CH]5=[CH]6CC[CH]7=[CH]8CC5)=Cc5ccccc5O1)[CH]1=[CH]2CC[CH]3=[CH]4CC1
• Title of publication: Polymorphs, enantiomorphs, chirality and helicity in [Rh{N,O}(η4-cod)] complexes with {N,O} = salicylaldiminato Schiff base or aminocarboxylato ligands
• Authors of publication: Janiak, Christoph; Chamayou, Anne-Christine; Royhan Uddin, A. K. M.; Uddin, Mohammad; Hagen, Karl S.; Enamullah, Mohammed
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 19
• Pages of publication: 3698 - 3709
• a: 10.6521 ± 0.0008 Å
• b: 11.9883 ± 0.0008 Å
• c: 12.0891 ± 0.0009 Å
• α: 77.496 ± 0.001°
• β: 89.989 ± 0.001°
• γ: 76.808 ± 0.001°
• Cell volume: 1465.43 ± 0.18 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0355
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.0735
• Weighted residual factors for all reflections included in the refinement: 0.0765
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No