Information card for entry 7001283

Structure parameters

• Chemical name: (η^4^-cycloocta-1,5-diene){(R)-N-(4-methoxphenyl)ethyl-2-oxo-1- naphthaldiminato-K^2^N,O}rhodium(I)
• Formula: C28 H30 N O2 Rh
• Calculated formula: C28 H30 N O2 Rh
• SMILES: [Rh]1234(Oc5ccc6c(c5C=[N]1[C@H](C)c1ccc(OC)cc1)cccc6)[CH]1=[CH]2CC[CH]3=[CH]4CC1
• Title of publication: Polymorphs, enantiomorphs, chirality and helicity in [Rh{N,O}(η4-cod)] complexes with {N,O} = salicylaldiminato Schiff base or aminocarboxylato ligands
• Authors of publication: Janiak, Christoph; Chamayou, Anne-Christine; Royhan Uddin, A. K. M.; Uddin, Mohammad; Hagen, Karl S.; Enamullah, Mohammed
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 19
• Pages of publication: 3698 - 3709
• a: 9.1961 ± 0.0002 Å
• b: 11.0473 ± 0.0003 Å
• c: 22.9704 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2333.61 ± 0.1 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.017
• Residual factor for significantly intense reflections: 0.0165
• Weighted residual factors for significantly intense reflections: 0.0442
• Weighted residual factors for all reflections included in the refinement: 0.0449
• Goodness-of-fit parameter for all reflections included in the refinement: 1.088
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No