Synthesis, structure and reactivity of tetranuclear square-type complexes of rhenium and manganese bearing pyrimidine-2-thiolate (pymS) ligands: versatile and efficient precursors for mono- and polynuclear compounds containing M(CO)3 (M = Re, Mn) fragments
Authors of publication
Kabir, S. E.; Alam, J.; Ghosh, S.; Kundu, K.; Hogarth, G.; Tocher, D. A.; Hossain, G. M. G.; Roesky, H. W.
Journal of publication
Dalton Transactions
Year of publication
2009
Journal issue
23
Pages of publication
4458 - 4467
a
22.372 ± 0.0004 Å
b
22.5986 ± 0.0005 Å
c
10.7794 ± 0.0002 Å
α
90°
β
90°
γ
90°
Cell volume
5449.8 ± 0.19 Å3
Cell temperature
120 ± 2 K
Ambient diffraction temperature
120 ± 2 K
Number of distinct elements
8
Space group number
62
Hermann-Mauguin space group symbol
P n m a
Hall space group symbol
-P 2ac 2n
Residual factor for all reflections
0.0448
Residual factor for significantly intense reflections
0.032
Weighted residual factors for significantly intense reflections
0.0703
Weighted residual factors for all reflections included in the refinement
0.0739
Goodness-of-fit parameter for all reflections included in the refinement
