Thermal and light-induced spin-transitions in iron(ii) complexes of 2,6-bis(4-halopyrazolyl)pyridines: the influence of polymorphism on a spin-crossover compound
Authors of publication
Pritchard, Ruth; Lazar, Hanane; Barrett, Simon A.; Kilner, Colin A.; Asthana, Saket; Carbonera, Chiara; Létard, Jean-François; Halcrow, Malcolm A.
Journal of publication
Dalton Transactions
Year of publication
2009
Journal issue
33
Pages of publication
6656 - 6666
a
16.329 ± 0.003 Å
b
3.813 ± 0.0007 Å
c
20.215 ± 0.003 Å
α
90°
β
104.231 ± 0.009°
γ
90°
Cell volume
1220 ± 0.4 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.1199
Residual factor for significantly intense reflections
0.0616
Weighted residual factors for significantly intense reflections
0.142
Weighted residual factors for all reflections included in the refinement
0.1631
Goodness-of-fit parameter for all reflections included in the refinement