Information card for entry 7003092

Structure parameters

• Chemical name: cis and trans -bis(diisopropylperfluorovinylphosphine)platinum(II) chloride
• Formula: C16 H28 Cl2 F6 P2 Pt
• Calculated formula: C16 H28 Cl2 F6 P2 Pt
• Title of publication: The coordination chemistry of perfluorovinyl substituted phosphine ligands, a crystallographic and spectroscopic study. Co-crystallisation of both cis- and trans-isomers of [PtCl2{PiPr2(CFCF2)}2] within the same unit cell
• Authors of publication: Barnes, Nicholas A.; Brisdon, Alan K.; Brown, F. R. William; Cross, Wendy I.; Herbert, Christopher J.; Pritchard, Robin G.; Sadiq, Ghazala
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 1
• Pages of publication: 101
• a: 8.1294 ± 0.0009 Å
• b: 16.184 ± 0.007 Å
• c: 25.965 ± 0.008 Å
• α: 90°
• β: 93.315 ± 0.015°
• γ: 90°
• Cell volume: 3410.4 ± 1.9 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0806
• Residual factor for significantly intense reflections: 0.0627
• Weighted residual factors for significantly intense reflections: 0.167
• Weighted residual factors for all reflections included in the refinement: 0.1842
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No