Information card for entry 7003094

Structure parameters

• Chemical name: bis(diiospropylperfluorovinylphospine)platium(II) diioide
• Formula: C16 H28 F6 I2 P2 Pt
• Calculated formula: C16 H28 F6 I2 P2 Pt
• SMILES: FC(=C(F)[P]([Pt](I)(I)[P](C(=C(F)F)F)(C(C)C)C(C)C)(C(C)C)C(C)C)F
• Title of publication: The coordination chemistry of perfluorovinyl substituted phosphine ligands, a crystallographic and spectroscopic study. Co-crystallisation of both cis- and trans-isomers of [PtCl2{PiPr2(CFCF2)}2] within the same unit cell
• Authors of publication: Barnes, Nicholas A.; Brisdon, Alan K.; Brown, F. R. William; Cross, Wendy I.; Herbert, Christopher J.; Pritchard, Robin G.; Sadiq, Ghazala
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 1
• Pages of publication: 101
• a: 12.6437 ± 0.0016 Å
• b: 12.9891 ± 0.0018 Å
• c: 14.5673 ± 0.0019 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2392.4 ± 0.5 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0549
• Residual factor for significantly intense reflections: 0.0434
• Weighted residual factors for significantly intense reflections: 0.1078
• Weighted residual factors for all reflections included in the refinement: 0.1129
• Goodness-of-fit parameter for all reflections included in the refinement: 1.101
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No