Information card for entry 7003096

Structure parameters

• Chemical name: bis(phenylbisperfluorovinyl)phosphine)platinum(II)dibromide
• Formula: C20 H10 Br2 F12 P2 Pt
• Calculated formula: C20 H10 Br2 F12 P2 Pt
• SMILES: [Pt](Br)(Br)([P](C(=C(F)F)F)(c1ccccc1)C(=C(F)F)F)[P](C(=C(F)F)F)(C(=C(F)F)F)c1ccccc1
• Title of publication: The coordination chemistry of perfluorovinyl substituted phosphine ligands, a crystallographic and spectroscopic study. Co-crystallisation of both cis- and trans-isomers of [PtCl2{PiPr2(CFCF2)}2] within the same unit cell
• Authors of publication: Barnes, Nicholas A.; Brisdon, Alan K.; Brown, F. R. William; Cross, Wendy I.; Herbert, Christopher J.; Pritchard, Robin G.; Sadiq, Ghazala
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 1
• Pages of publication: 101
• a: 11.3236 ± 0.0003 Å
• b: 13.3972 ± 0.0002 Å
• c: 16.7449 ± 0.0002 Å
• α: 90°
• β: 106.182 ± 0.002°
• γ: 90°
• Cell volume: 2439.63 ± 0.08 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0712
• Residual factor for significantly intense reflections: 0.0382
• Weighted residual factors for significantly intense reflections: 0.0622
• Weighted residual factors for all reflections included in the refinement: 0.0705
• Goodness-of-fit parameter for all reflections included in the refinement: 1.017
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No