A series of metal complexes with the non-innocent N,N′-bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure
Authors of publication
Khusniyarov, Marat M.; Harms, Klaus; Burghaus, Olaf; Sundermeyer, Jörg; Sarkar, Biprajit; Kaim, Wolfgang; van Slageren, Joris; Duboc, Carole; Fiedler, Jan
Journal of publication
Dalton Transactions
Year of publication
2008
Journal issue
10
Pages of publication
1355 - 1365
a
15.0923 ± 0.0014 Å
b
19.202 ± 0.0014 Å
c
35.566 ± 0.003 Å
α
90°
β
90°
γ
90°
Cell volume
10307.1 ± 1.5 Å3
Cell temperature
193 ± 2 K
Ambient diffraction temperature
193 ± 2 K
Number of distinct elements
6
Space group number
70
Hermann-Mauguin space group symbol
F d d d :2
Hall space group symbol
-F 2uv 2vw
Residual factor for all reflections
0.0689
Residual factor for significantly intense reflections
0.0458
Weighted residual factors for significantly intense reflections
0.0987
Weighted residual factors for all reflections included in the refinement
0.1064
Goodness-of-fit parameter for all reflections included in the refinement
