Information card for entry 7003428

Structure parameters

• Formula: C40 H69 N3 P Rh Si4 Sn
• Calculated formula: C40 H69 N3 P Rh Si4 Sn
• SMILES: [c]123[cH]4[cH]5[cH]6[cH]7[cH]1[Rh]34567([P](C(C)C)(C(C)C)C(C)C)[Sn]13N([C@@H]2C)[Si](C)(C)[Si](C)([Si](C)(C)N1[C@H](C)c1ccccc1)[Si](C)(C)N3[C@H](C)c1ccccc1
• Title of publication: A chiral stannate as an “ansa” π-arene ligand in rhodium chemistry
• Authors of publication: Kilian, Michaela; Wadepohl, Hubert; Gade, Lutz H.
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 5
• Pages of publication: 582 - 584
• a: 22.7301 ± 0.0014 Å
• b: 10.6279 ± 0.0006 Å
• c: 21.0608 ± 0.0012 Å
• α: 90°
• β: 115.504 ± 0.001°
• γ: 90°
• Cell volume: 4592 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Residual factor for all reflections: 0.0265
• Residual factor for significantly intense reflections: 0.0237
• Weighted residual factors for significantly intense reflections: 0.0512
• Weighted residual factors for all reflections included in the refinement: 0.0522
• Goodness-of-fit parameter for all reflections included in the refinement: 1.084
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No