Information card for entry 7003688

Structure parameters

• Formula: C47 H67 O P3 Rh2
• Calculated formula: C47 H67 O P3 Rh2
• SMILES: [Rh]1234([PH](P([Rh]567([PH]1c1c(cc(cc1C)C)C)[CH]1=[CH]5CC[CH]6=[CH]7CC1)c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)[CH]1=[CH]2CC[CH]3=[CH]4CC1.O1CCCC1
• Title of publication: Different transmetallation behaviour of [M(P4HR4)] salts toward rhodium(i) and copper(i) (M = Na, K; R = Ph, Mes; Mes = 2,4,6-Me3C6H2)
• Authors of publication: Gómez-Ruiz, Santiago; Wolf, Robert; Hey-Hawkins, Evamarie
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 15
• Pages of publication: 1982 - 1988
• a: 12.627 ± 0.005 Å
• b: 12.941 ± 0.005 Å
• c: 15.604 ± 0.005 Å
• α: 74.908 ± 0.005°
• β: 84.544 ± 0.005°
• γ: 67.189 ± 0.005°
• Cell volume: 2269.2 ± 1.5 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0904
• Residual factor for significantly intense reflections: 0.0495
• Weighted residual factors for significantly intense reflections: 0.153
• Weighted residual factors for all reflections included in the refinement: 0.1728
• Goodness-of-fit parameter for all reflections included in the refinement: 0.995
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No