Information card for entry 7003692

Structure parameters

• Formula: C27 H45 Al N2 Si2
• Calculated formula: C27 H45 Al N2 Si2
• SMILES: [Si](N1[Al]([N]([Si](C)(C)C)=C(C=C1c1ccccc1)C12CC3CC(C1)CC(C2)C3)(C)C)(C)(C)C
• Title of publication: Synthesis and structures of crystalline Li, Al and Sn(ii) 1-azaallyls and β-diketiminates derived from [Li{μ,η3-N(SiMe3)C(Ad)C(H)SiMe3}]2 (Ad = 1-adamantyl)
• Authors of publication: Bourget-Merle, Laurence; Hitchcock, Peter B.; Lappert, Michael F.; Merle, Philippe G.
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 26
• Pages of publication: 3493 - 3501
• a: 6.5294 ± 0.0002 Å
• b: 12.4764 ± 0.0004 Å
• c: 17.8535 ± 0.0007 Å
• α: 97.866 ± 0.002°
• β: 93.585 ± 0.002°
• γ: 98.304 ± 0.002°
• Cell volume: 1420.58 ± 0.08 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0537
• Residual factor for significantly intense reflections: 0.0435
• Weighted residual factors for significantly intense reflections: 0.1112
• Weighted residual factors for all reflections included in the refinement: 0.1184
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No