Information card for entry 7003836

Structure parameters

• Formula: C32 H72 N2 P6 Si4 Sn
• Calculated formula: C32 H72 N2 P6 Si4 Sn
• Title of publication: Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P‒P bond of the hexaphospha-pentaprismane cage, P6C4tBu4: Crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2 -2,6)
• Authors of publication: Al-Ktaifani, Mahmoud M.; Hitchcock, Peter B.; Lappert, Michael F.; Nixon, John F.; Uiterweerd, Philip
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 21
• Pages of publication: 2825 - 2831
• a: 11.9453 ± 0.0017 Å
• b: 13.7446 ± 0.0014 Å
• c: 15.126 ± 0.002 Å
• α: 114.191 ± 0.007°
• β: 93.524 ± 0.005°
• γ: 94.335 ± 0.009°
• Cell volume: 2247.2 ± 0.5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1024
• Residual factor for significantly intense reflections: 0.0607
• Weighted residual factors for significantly intense reflections: 0.1202
• Weighted residual factors for all reflections included in the refinement: 0.1356
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No