Information card for entry 7003919

Structure parameters

• Formula: C50 H44 Br2 O1.5 P2 Pt
• Calculated formula: C50 H44 Br2 O1.5 P2 Pt
• Title of publication: Selective carbon‒carbon bond cleavage of 2,2′-dibromotolane via photolysis of its appropriate (diphosphine)Pt0 complex in the solid state
• Authors of publication: Petzold, Holm; Weisheit, Thomas; Görls, Helmar; Breitzke, Hergen; Buntkowsky, Gerd; Escudero, Daniel; González, Leticia; Weigand, Wolfgang
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 15
• Pages of publication: 1979 - 1981
• a: 21.3703 ± 0.0006 Å
• b: 13.6258 ± 0.0003 Å
• c: 15.604 ± 0.0003 Å
• α: 90°
• β: 93.29 ± 0.001°
• γ: 90°
• Cell volume: 4536.2 ± 0.18 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0819
• Residual factor for significantly intense reflections: 0.0488
• Weighted residual factors for significantly intense reflections: 0.1059
• Weighted residual factors for all reflections included in the refinement: 0.1194
• Goodness-of-fit parameter for all reflections included in the refinement: 1.015
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα?
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No