Information card for entry 7003970

Structure parameters

• Common name: (PhInd)2GdNTMS
• Formula: C36 H40 Gd N Si2
• Calculated formula: C36 H40 Gd N Si2
• SMILES: [Gd]12345678(N([Si](C)(C)C)[Si](C)(C)C)([c]9([cH]2[c]23cccc[c]42[cH]19)c1ccccc1)[c]1([cH]5[c]28[c]7([cH]61)cccc2)c1ccccc1
• Title of publication: Generation of cationic indenyl silylamide gadolinium and scandium complexes [(Ind)Ln{N(SiMe3)2}]+[B(C6F5)4]− and their reactivity for 1,3-butadiene polymerization
• Authors of publication: Tardif, Olivier; Kaita, Shojiro
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 19
• Pages of publication: 2531 - 2533
• a: 9.772 ± 0.003 Å
• b: 9.914 ± 0.002 Å
• c: 17.75 ± 0.006 Å
• α: 77.26 ± 0.03°
• β: 75.6 ± 0.03°
• γ: 77.78 ± 0.03°
• Cell volume: 1602 ± 0.8 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0486
• Residual factor for significantly intense reflections: 0.0393
• Weighted residual factors for significantly intense reflections: 0.0768
• Weighted residual factors for all reflections included in the refinement: 0.0793
• Goodness-of-fit parameter for all reflections included in the refinement: 0.929
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No