Information card for entry 7004018

Structure parameters

• Formula: C52 H46 N3 P2 Rh
• Calculated formula: C52 H46 N3 P2 Rh
• Title of publication: Functionalized phosphorus analogues of the β-diketiminato ligand systems: bis(N-arylphosphinimino)acetonitrile-derived complexes of rhodium and iridium
• Authors of publication: Spannhoff, Kirsten; Kehr, Gerald; Kehr, Seda; Fröhlich, Roland; Erker, Gerhard
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 25
• Pages of publication: 3339 - 3344
• a: 9.978 ± 0.0001 Å
• b: 20.7312 ± 0.0003 Å
• c: 41.3429 ± 0.0007 Å
• α: 90°
• β: 91.05 ± 0.001°
• γ: 90°
• Cell volume: 8550.6 ± 0.2 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0979
• Residual factor for significantly intense reflections: 0.0634
• Weighted residual factors for significantly intense reflections: 0.1422
• Weighted residual factors for all reflections included in the refinement: 0.1652
• Goodness-of-fit parameter for all reflections included in the refinement: 1.003
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No