Information card for entry 7004394

Structure parameters

• Formula: C36 H60 O4 Rh4 Si2
• Calculated formula: C36 H60 O4 Rh4 Si2
• SMILES: [Rh]1234([O]5[Rh]678([O]9[Rh]%10%11%12([O]([Rh]%13%14%15([O]1[Si]9(C)C)[CH]1=[CH]%13CC[CH]%14=[CH]%15CC1)[Si]5(C)C)[CH]1=[CH]%10CC[CH]%11=[CH]%12CC1)[CH]1=[CH]6CC[CH]7=[CH]8CC1)[CH]1=[CH]2CC[CH]3=[CH]4CC1
• Title of publication: Flexible coordination of bulky amidinates and guanidinates towards rhodium(i): conversion of kinetic to thermodymanic isomers
• Authors of publication: Jones, Cameron; Mills, David P.; Stasch, Andreas
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 35
• Pages of publication: 4799 - 4804
• a: 11.7331 ± 0.0002 Å
• b: 18.52 ± 0.0003 Å
• c: 19.0441 ± 0.0003 Å
• α: 111.723 ± 0.001°
• β: 97.088 ± 0.001°
• γ: 97.293 ± 0.001°
• Cell volume: 3747.5 ± 0.11 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0508
• Residual factor for significantly intense reflections: 0.0414
• Weighted residual factors for significantly intense reflections: 0.0749
• Weighted residual factors for all reflections included in the refinement: 0.0819
• Goodness-of-fit parameter for all reflections included in the refinement: 1.139
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No