Information card for entry 7004605

Structure parameters

• Formula: C49.5 H48 Cl2 N5 O3 P3 Ru
• Calculated formula: C49.5 H48 Cl2 N5 O3 P3 Ru
• Title of publication: Novel ruthenium(ii) complexes containing the N-phosphorylated iminophosphorane-phosphine ligand Ph2PCH2P{NP(O)(OEt)2}Ph2: a new coordination mode of its methanide anion
• Authors of publication: Cadierno, Victorio; Díez, Josefina; García-Álvarez, Joaquín; Gimeno, José; Rubio-García, Javier
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 42
• Pages of publication: 5737 - 5748
• a: 10.186 ± 0.0006 Å
• b: 12.3134 ± 0.0007 Å
• c: 21.386 ± 0.0013 Å
• α: 96.78 ± 0.005°
• β: 100.137 ± 0.005°
• γ: 113.644 ± 0.005°
• Cell volume: 2365.3 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1063
• Residual factor for significantly intense reflections: 0.0607
• Weighted residual factors for significantly intense reflections: 0.1433
• Weighted residual factors for all reflections included in the refinement: 0.1667
• Goodness-of-fit parameter for all reflections included in the refinement: 0.927
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No