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Information card for entry 7004858
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Coordinates | 7004858.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | trans(P,N)-(N,N-Dimethyldithiocarbamato)bis((3- aminopropyl)dimethylphosphine) cobalt(iii) Bis(tetraphenylborate) |
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Chemical name | trans(P,N)-(N,N-Dimethyldithiocarbamato)bis((3-aminopropyl)dimethylphosphine) cobalt(III) Bis(tetraphenylborate) |
Formula | C61 H74 B2 Co N3 P2 S2 |
Calculated formula | C61 H74 B2 Co N3 P2 S2 |
SMILES | [Co]123([S]=C(S1)N(C)C)([P](C)(C)CCC[NH2]2)[P](C)(C)CCC[NH2]3.c1(ccccc1)[B-](c1ccccc1)(c1ccccc1)c1ccccc1.c1(ccccc1)[B-](c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Preparation and characterization of mixed-ligand cobalt(III) complexes containing (3-aminopropyl)dimethylphosphine (pdmp). Conformation of the six-membered pdmp chelate ring. |
Authors of publication | Suzuki, Takayoshi; Fujiiwara, Katsuhiro; Takagi, Hideo D.; Kashiwabara, Kazuo |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2007 |
Journal issue | 3 |
Pages of publication | 308 - 319 |
a | 17.854 ± 0.004 Å |
b | 14.294 ± 0.004 Å |
c | 22.041 ± 0.005 Å |
α | 90° |
β | 93.825 ± 0.009° |
γ | 90° |
Cell volume | 5612 ± 2 Å3 |
Cell temperature | 296 ± 2 K |
Ambient diffraction temperature | 296 ± 2 K |
Number of distinct elements | 7 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.052 |
Residual factor for significantly intense reflections | 0.0394 |
Weighted residual factors for significantly intense reflections | 0.1126 |
Weighted residual factors for all reflections included in the refinement | 0.1205 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.055 |
Diffraction radiation wavelength | 0.71075 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7004858.html
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