Information card for entry 7005244

Structure parameters

• Formula: C75.5 H76 Cl O8 P4 Ru2
• Calculated formula: C75.5 H76 Cl O8 P4 Ru2
• Title of publication: Bis(acetylacetonato)ruthenium(II) complexes containing alkynyldiphenylphosphines. Formation and redox behaviour of [Ru(acac)2(Ph2PC triple bond CR)2] (R=H, Me, Ph) complexes and the binuclear complex cis-[{Ru(acac)2}2(micro-Ph2PC triple bond CPPh2)}2].
• Authors of publication: Bennett, Martin A.; Byrnes, Matthew J.; Willis, Anthony C.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 17
• Pages of publication: 1677 - 1686
• a: 12.096 ± 0.004 Å
• b: 22.508 ± 0.004 Å
• c: 27.778 ± 0.003 Å
• α: 90°
• β: 102.41 ± 0.02°
• γ: 90°
• Cell volume: 7386 ± 3 ų
• Cell temperature: 193.2 K
• Ambient diffraction temperature: 193.2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0521
• Residual factor for significantly intense reflections: 0.0393
• Weighted residual factors for all reflections: 0.0523
• Weighted residual factors for significantly intense reflections: 0.0444
• Weighted residual factors for all reflections included in the refinement: 0.0444
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1497
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No