Information card for entry 7005331

Structure parameters

• Formula: C32 H28 I2 Ir N6 O4 Rh
• Calculated formula: C32 H28 I2 Ir N6 O4 Rh
• Title of publication: Iodination of triazenide-bridged rhodium and iridium complexes: oxidative addition vs. one-electron oxidation.
• Authors of publication: Adams, Christopher J.; Baber, R. Angharad; Connelly, Neil G.; Harding, Phimphaka; Hayward, Owen D.; Kandiah, Mathivathani; Orpen, A. Guy
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 13
• Pages of publication: 1325 - 1333
• a: 20.513 ± 0.005 Å
• b: 8.4782 ± 0.0015 Å
• c: 21.624 ± 0.003 Å
• α: 90°
• β: 110.566 ± 0.015°
• γ: 90°
• Cell volume: 3521 ± 1.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0492
• Residual factor for significantly intense reflections: 0.0305
• Weighted residual factors for significantly intense reflections: 0.0721
• Weighted residual factors for all reflections included in the refinement: 0.0788
• Goodness-of-fit parameter for all reflections included in the refinement: 0.982
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No