Information card for entry 7005501

Structure parameters

• Common name: Hexacarbonyl-bis(9-ethyl-9-phosphabicyclo(3.3.1)nonane)- dicobalt
• Chemical name: Hexacarbonyl-bis(9-ethyl-9-phosphabicyclo[3.3.1]nonane)-dicobalt
• Formula: C26 H38 Co2 O6 P2
• Calculated formula: C26 H38 Co2 O6 P2
• Title of publication: Bicyclic phosphines as ligands for cobalt catalysed hydroformylation. Crystal structures of [Co(Phoban[3.3.1]-Q)(CO)(3)](2) (Q = C(2)H(5), C(5)H(11), C(3)H(6)NMe(2), C(6)H(11)).
• Authors of publication: Bungu, Peter N.; Otto, Stefanus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 27
• Pages of publication: 2876 - 2884
• a: 11.403 ± 0.002 Å
• b: 14.964 ± 0.003 Å
• c: 16.632 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2838 ± 0.9 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 64
• Hermann-Mauguin space group symbol: C m c a
• Hall space group symbol: -C 2ac 2
• Residual factor for all reflections: 0.1004
• Residual factor for significantly intense reflections: 0.0925
• Weighted residual factors for significantly intense reflections: 0.2109
• Weighted residual factors for all reflections included in the refinement: 0.2145
• Goodness-of-fit parameter for all reflections included in the refinement: 1.199
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No